Kinetics
____ 1. Which of the five factors listed does not
affect the rate of a homogeneous reaction?
|
a. |
the presence of catalysts |
|
b. |
the concentrations of reactants |
|
c. |
the temperature of the reaction system |
|
d. |
the surface area of the reactants |
|
e. |
the properties of the reactants and the
products |
____ 2. Which statement describes a correct approach
to determining the rate law for a reaction?
|
a. |
Balance the chemical equation and use the
coefficients of the reactants as exponents for the concentrations of
reactants. |
|
b. |
Balance the chemical equation and use
the coefficients of the reactants as factors for the concentrations. |
|
c. |
Balance the chemical equation and use
the reciprocals of the coefficients of the reactants as factors for the
concentrations. |
|
d. |
Perform experiments in which the initial
rate of the reaction is measured using varying amounts of each reactant. |
|
e. |
Perform experiments in which the concentration
of each reactant is measured at specific time intervals. |
____ 3. The rate constant for the first order
decomposition of SO2Cl2 at a very high temperature is
1.37 ´ 10-3 min-1. If the initial
concentration is 0.500 M, predict the concentration after five hours (300 min).
|
a. |
0.500 M |
|
b. |
6.85 ´ 10-4 M |
|
c. |
0.331 M |
|
d. |
1.33 M |
|
e. |
0.754 M |
____ 4. When the structure of only one atom, molecule
or ion is rearranged to produce a new species, the process is called a(an)
|
a. |
activated complex |
|
b. |
activation energy |
|
c. |
bimolecular reaction |
|
d. |
steric factor |
|
e. |
unimolecular reaction |
____ 5. When two particles must collide to produce a
new species, the process is called a(an)
|
a. |
activated complex |
|
b. |
activation energy |
|
c. |
bimolecular reaction |
|
d. |
steric factor |
|
e. |
unimolecular reaction |
____ 6. Which of the following factors increases the
rate of a chemical reaction by increasing the number of molecules with enough
energy to overcome the activation energy barrier?
|
a. |
increasing the temperature |
|
b. |
increasing the concentration of reactants |
|
c. |
increasing the concentration of products |
|
d. |
adding a catalyst |
|
e. |
increasing the surface area of a phase
interface |
____ 8. The solid catalysts used in many industrial processes
where the reactants are liquids or gases are referred to as
|
a. |
enzymes. |
|
b. |
heterogeneous catalysts. |
|
c. |
homogeneous catalysts. |
|
d. |
silicon catalysts. |
|
e. |
zeolites. |
74. In your own words distinguish between the average
rate of a reaction over a certain time interval and the instantaneous reaction
rate at a particular time.
75. Sketch a reaction diagram for the endothermic
conversion of A ®
B, where the activation energy is 50 kJ/mol, and the DE, which = DH, is 25 kJ/mol. Label the reactant as A, the product as B, the
activated complex or transition state as AC, the activation energy as Ea, and the
reaction energy as DE.
76. Consider the reaction with the mechanism
shown:
|
2NO |
® |
N2O2 |
|
|
|
|
slow |
|
N2O2 |
+ |
H2 |
® |
N2O |
+ |
H2O |
fast |
|
N2O |
+ |
H2 |
® |
N2 |
+ |
H2O |
fast |
a. Write the overall reaction represented
by this mechanism.
b. What are the intermediates in this
reaction, if any?
c. What are the catalysts in this
reaction, if any?
d. Write the rate law for this reaction.
Explain your answer.
Equilibrium
____ 9. Consider the reaction
COCl2(g)
<===> CO(g) + Cl2(g)
At equilibrium, [CO] = 4.14 ´ 10-6 M; [Cl2] =
4.14 ´ 10-6 M; and [COCl2]
= 0.0627 M. Calculate the value of the equilibrium constant.
|
a. |
1.32 ´ 10-4 |
|
b. |
1.51 ´ 104 |
|
c. |
2.73 ´ 10-10 |
|
d. |
3.66 ´ 109 |
|
e. |
6.60 ´ 10-5 |
____ 10. Consider the reaction system:
2N2(g)
+ O2(g) ¬¾® 2N2O(g)
Kc = 1.5 ´ 10-30
At equilibrium, the concentration of N2
was measured as 0.048 M and the concentration of O2 as 0.093 M. What
is the concentration of N2O in this system?
|
a. |
8.2 ´ 10-17 |
|
b. |
1.8 ´ 10-17 |
|
c. |
4.7 ´ 10-27 |
|
d. |
3.4 ´ 10-28 |
|
e. |
3.2 ´ 10-34 |
____ 11. Consider the equilibrium system
C(s)
+ CO2(g) <====> 2CO(g)
If CO2 is added, the
equilibrium will ____, and if CO is added the equilibrium will ____.
|
a. |
shift forward; shift reverse |
|
b. |
shift forward; shift forward |
|
c. |
shift reverse; shift reverse |
|
d. |
be unchanged; shift forward |
|
e. |
neither can be predicted |
____ 12. Consider the equilibrium system
C(s)
+ CO2(g) <====> 2CO(g)
If the pressure on the system is increased
the equilibrium will _____, because _____.
|
a. |
shift forward; higher pressure favors
fewer moles of gas |
|
b. |
shift forward; higher pressure favors
more moles of gas |
|
c. |
shift reverse; higher pressure favors
fewer moles of gas |
|
d. |
shift reverse; higher pressure favors
more moles of gas |
|
e. |
be unchanged; of the presence of the
solid C |
____ 13. Considering only the probability factor in the
gaseous reaction 2A + B <===> C, the ____ side is favored because ____.
|
a. |
product; there are more possible
arrangements of molecules on the reactant side |
|
b. |
product; there are more possible
arrangements of molecules on the product side |
|
c. |
reactant; there are more possible
arrangements of molecules on the reactant side |
|
d. |
reactant; there are more possible
arrangements of molecules on the product side |
|
e. |
More information is needed to determine
which side is favored. |
____ 14. Which statement concerning product-favored
reactions is not correct?
|
a. |
The value of the equilibrium constant is
greater than 1. |
|
b. |
An endothermic reaction is
product-favored. |
|
c. |
If the entropy of the products is greater
than the entropy of the reactants, the reaction is product-favored. |
|
d. |
If a reaction is product-favored at high
temperature, the entropy of the products is probably greater than the entropy
of the reactants. |
|
e. |
If a reaction is product-favored at low
temperature, the enthalpy of the products is probably less than the enthalpy
of the reactants. |
77. Consider the
statement, "At equilibrium, no chemistry is occurring because the reaction
has been completed."
a. Is this statement true or false?
b. Explain your answer in detail. Be sure
to consider the situation both from a macroscopic viewpoint and a nanoscale
viewpoint.
78. The
interhalogen compound bromine chloride is formed by the reaction of bromine
vapor and chlorine gas. The compound is a gas at the temperature of this
reaction.
a. Write the balanced equation for the
reaction. Also write the Kc expression.
b. Kc = 6.87 and a 2.00 L flask
initially contains chlorine at a concentration of 0.51 M and bromine at a
concentration of 0.34 M. When equilibrium is reached, the concentration of
bromine chloride is 0.46 M. Calculate the equilibrium concentrations of bromine
and chlorine.
c. Consider the reaction system in part b.
In what direction will the reaction shift if the volume of the container is
increased to 4.0 L? _____ Explain your answer.
d. Consider the reaction system in part b.
In what direction will the reaction shift if bromine chloride is added? _____
Explain your answer.
e. Consider the reaction system in part b.
In what direction will the reaction shift if a catalyst is added? _____ Explain
your answer.
Solutions
____ 15. A solution is a
|
a. |
homogeneous mixture of two or more
substances. |
|
b. |
heterogeneous mixture of at least three
substances. |
|
c. |
mixture of two or more substances in
which the heavier particles can "settle out." |
|
d. |
homogeneous mixture of an element with a
compound. |
|
e. |
homogenous mixture containing two or
more compounds. |
____ 16. If a liquid is miscible with water, some
portion of the molecule is _____, which means that it is _____.
|
a. |
polar; hydrophobic |
|
b. |
polar; hydrophilic |
|
c. |
nonpolar; hydrophobic |
|
d. |
nonpolar; hydrophilic |
|
e. |
bipolar; insoluble |
____ 17. When a solution is saturated the concentration
of the solute is _____ the solubility, and _____ solute will dissolve.
|
a. |
greater than; more |
|
b. |
greater than; no more |
|
c. |
equal to; no more |
|
d. |
less than; no more |
|
e. |
less than; more |
____ 19. The unit M means _____, which is defined as
_____.
|
a. |
molality; moles solute/mole solvent |
|
b. |
molality; moles solute/kg solvent |
|
c. |
molarity; mass solute/mass solution |
|
d. |
molarity; moles solute/mole solvent |
|
e. |
molarity; moles solute/liter solution |
____ 20. What is the molarity of technical grade
concentrated sulfuric acid, H2SO4, which is labeled 95% and
has a density of 1.84 g/mL?
|
a. |
0.969 M |
|
b. |
1.84 M |
|
c. |
17.8 M |
|
d. |
51.6 M |
|
e. |
98.0 M |
____ 21. An aqueous solution at 27°C contains 4.2 g of a protein in a 200. mL
sample. The osmotic pressure is 0.0237 atm. What is the molar mass of the
protein?
|
a. |
2.2 ´ 104 g/mol |
|
b. |
870 g/mol |
|
c. |
2.0 ´ 103 g/mol |
|
d. |
79 g/mol |
|
e. |
22 g/mol |
____ 22. In living systems, a solution that is ____ has
a lower solute concentration than the surrounding cells and therefore causes
water to flow _____ the cells by osmosis.
|
a. |
hypertonic; into |
|
b. |
hypotonic; into |
|
c. |
isotonic; into |
|
d. |
hypertonic; out of |
|
e. |
hypotonic; out of |
79. Explain the arrangement of these compounds in
order of increasing solubility in water:
CH3(CH2)5CH3
< CH3(CH2)5OH < HO(CH2)5OH
80. The solubility of sodium acetate, NaC2H3O2,
is 75 g/100 mL. Determine whether a solution containing 365 g NaC2H3O2
in 475 mL water is unsaturated, saturated, or supersaturated. Show a
calculation to support your answer.
Acids and Bases
____ 25. The reaction between ethylamine, an organic
base, and hydrochloric acid is written as _____. The formula for ethylamine is
CH3CH2NH2.
|
a. |
CH3CH2NH2 +
HCl <===> CH4CH2NH2+Cl- |
|
b. |
CH3CH2NH2 +
HCl <===> CH3CH3NH2+Cl- |
|
c. |
CH3CH2NH2 +
2HCl <===> CH3CH2NH42+Cl2- |
|
d. |
CH3CH2NH2 +
HCl <===> CH3CH2NH3+Cl- |
|
e. |
CH3CH2NH2 +
HCl <===> CH3CH2NH-H2Cl+ |
____ 26. Calculate the [H+] and [OH-]
in a 1.2 M KOH solution, a strong base. [H+] = _____, and [OH-]
= _____.
|
a. |
1.2 M; 1.2 M |
|
b. |
1.2 M; 8.3 ´ 10-15 M |
|
c. |
8.3 ´ 10-15 M; 1.2 M |
|
d. |
8.3 ´ 10-15 M; 1.0 ´ 10-14 M |
|
e. |
1.0 ´ 10-7 M; 1.0 ´ 10-7 M |
____ 27. Calculate the [H+] and [OH-]
in a 1.2 M HClO4 solution, a strong acid. [H+] = _____,
and [OH-] = _____.
|
a. |
1.2 M; 1.2 M |
|
b. |
1.2 M; 8.3 ´ 10-15 M |
|
c. |
8.3 ´ 10-15 M; 1.2 M |
|
d. |
8.3 ´ 10-15 M; 1.0 ´ 10-14 M |
|
e. |
1.0 ´ 10-7 M; 1.0 ´ 10-7 M |
____ 28. Calculate the pH of a solution where [OH-]
= 4.6 ´ 10-4. Is this solution acidic
or basic?
|
a. |
4.60; basic |
|
b. |
10.66; basic |
|
c. |
10.66; acidic |
|
d. |
3.34; basic |
|
e. |
3.34; acidic |
____ 29. Which statement about a 0.50 M sample of the weak
acid, HNO2, Ka = 4.5 ´ 10-4, is not correct?
|
a. |
[H+] = 0.50 M. |
|
b. |
The acid is only slightly ionized. |
|
c. |
The sample contains mostly un-ionized
HNO2 molecules. |
|
d. |
The pH is slightly less than 2.0. |
|
e. |
[H+] > [OH-]. |
____ 30. For the basic compound strychnine, the value
of Kb is 1.8 ´ 10-6.
What is the pH of a 0.085 M solution of this poison?
|
a. |
3.41 |
|
b. |
6.81 |
|
c. |
7.18 |
|
d. |
10.59 |
|
e. |
11.66 |
____ 31. Acid-base chemistry causes some baked goods to
"rise" by producing
|
a. |
carbon dioxide when an acid reacts with
sodium bicarbonate in baking soda. |
|
b. |
hydrogen gas from trace metals that
react with acids in the batter. |
|
c. |
steam from the water formed in
neutralization. |
|
d. |
carbon dioxide and ethanol as
fermentation products. |
|
e. |
sulfur dioxide from sulfite-containing
foods. |
____ 32. The association between a Lewis acid and a
Lewis base is called a(an) _____ bond.
|
a. |
acidic |
|
b. |
coordinate covalent |
|
c. |
hydrogen |
|
d. |
ionic |
|
e. |
metallic |
82. a. Write the
reaction for the ionization of the weak acid HA in water.
b. Write the reaction for the ionization
of the conjugate base of the weak acid HA in water.
c. Using equilibrium constant expressions
for the reaction of HA and its conjugate base A- with water, show
why the product of Ka and Kb is always equal to 10-14 at 25°C.
More Aqueous
Equilibria
____ 33. Which pair of compounds could be used to make
a buffer solution?
|
a. |
NaCl/HCl |
|
b. |
(NH4)2SO4/H2SO4 |
|
c. |
NaCH3COO/CH3COOH |
|
d. |
K3PO4/KH2PO4 |
|
e. |
KOH/KBr |
____ 34. Which formula represents the
Henderson-Hasselbalch equation for the generic acid HA?
|
a. |
|
|
b. |
|
|
c. |
|
|
d. |
|
|
e. |
|
____ 36. Write the Ksp expression for silver phosphate,
Ag3PO4.
|
a. |
[Ag+]3[PO43-] |
|
b. |
|
|
c. |
3x[Ag+][PO43-] |
|
d. |
3x[Ag+]3 + [PO43-] |
|
e. |
[H+][OH-] |
____ 37. Calculate the molar solubility of silver chloride,
AgCl, in a solution in which [Cl-] = 0.045 M. Ksp = 1.8 ´ 10-10 for silver chloride.
|
a. |
1.3 ´ 10-5 |
|
b. |
2.5 ´ 10-8 |
|
c. |
4.0 ´ 10-9 |
|
d. |
1.8 ´ 10-10 |
|
e. |
8.1 ´ 10-12 |
____ 38. In which solution would calcium phosphate have
the greatest solubility?
|
a. |
0.1 M phosphoric acid |
|
b. |
0.1 M sodium phosphate |
|
c. |
saturated calcium hydroxide |
|
d. |
0.1 M calcium nitrate |
|
e. |
distilled water |
____ 39. Which mixture would dissolve the largest
amount of barium sulfate?
|
a. |
0.1 M HCl |
|
b. |
0.1 M Ba(NO3)2 |
|
c. |
0.1 M Mg(OH)2 |
|
d. |
0.1 M Na2SO4 |
|
e. |
0.1 M Al2(SO4)3 |
83. How will the
addition of 0.1 M NH3 to a saturated solution of CuCO3
affect the solubility of the CuCO3? Show a calculation to support
your answer.
Ksp for copper(II) carbonate = 2.5 ´ 10-10
Kf for copper(II) tetraammine = 1.1 ´ 1013
84. Consider two
saturated solutions, one of CuCO3 and one of Cu3(PO4)2.
How will each solution be affected by the addition of 0.1 M NH3?
Show a calculation to support your answer.
Ksp for copper(II) carbonate = 2.5 ´ 10-10
Ksp for copper(II) phosphate = 1.4 ´ 10-37
Kf for copper(II) tetraammine = 1.1 ´ 1013
Kb for ammonia = 1.8 ´ 10-5
Thermodynamics
____ 40. If a coin is tossed five times, which of the
arrangements shown is least likely?
|
a. |
THTHT |
|
b. |
HHTHT |
|
c. |
THHTT |
|
d. |
TTTHT |
|
e. |
HTTHT |
____ 41. Which statement about entropy is not correct?
|
a. |
The entropy of a particular sample is
greater in the gaseous state than in the solid state. |
|
b. |
In considering a series of similar, but
increasingly larger molecules all in the same state, the largest molecule
will have greatest entropy. |
|
c. |
Because of the larger charges, the
entropy of CaO is less than the entropy of KF. |
|
d. |
Entropy decreases when ethanol, C2H5OH,
dissolves in water. |
|
e. |
A bottle of carbonated water has lower entropy
than the same masses of carbon dioxide gas and distilled water. |
____ 42. Which process illustrates a decrease in
entropy?
|
a. |
baking a cake from scratch |
|
b. |
making tossed salad |
|
c. |
producing aluminum foil from bauxite ore |
|
d. |
shuffling a deck of cards |
|
e. |
spreading grass seed on a lawn |
____ 43. Calculate the value of DS° for the reaction shown:
C3H8(g) + 5O2(g) ® 4H2O(g) +
3CO2(g)
At 25°C the values of entropy in J/mol-K are propane, 270.2; oxygen, 205.15;
water, 188.74; carbon dioxide, 213.80.
|
a. |
-100.41 J/K |
|
b. |
-72.81 J/K |
|
c. |
72.81 J/K |
|
d. |
100.41 J/K |
|
e. |
921.01 J/K |
____ 44. Calculate the value of DS° for the reaction shown:
N2(g) + 3H2(g) ® 2NH3(g)
At 25°C the values of entropy in J/mol-K are nitrogen, 191.61: hydrogen,
130.68; and ammonia, 192.77.
|
a. |
-969.19 J/K |
|
b. |
-393.20 J/K |
|
c. |
-390.88 J/K |
|
d. |
-198.11 J/K |
|
e. |
-129.52 J/K |
____ 45. According to the second law of thermodynamics,
|
a. |
any process in which entropy increases
will be product-favored. |
|
b. |
any process which is endothermic will be
product-favored. |
|
c. |
only processes in which the entropy of the
universe is increasing will be product-favored. |
|
d. |
heat will always be transferred from a
warmer object to a cooler object. |
|
e. |
the total amount of matter in the
universe remains constant. |
____ 46. Which statement regarding the Gibbs free
energy of a system is not correct?
|
a. |
It is defined as -TDSuniverse. |
|
b. |
In a product-favored reaction, its value
is less than zero. |
|
c. |
Its value is a function of DSsurroundings and DSsystem. |
|
d. |
Its value is zero when DHsystem = DSsystem. |
|
e. |
The previous four statements are all
correct. |
____ 47. The value of the equilibrium constant for a
reaction is 2.65 ´ 10-6
at 35°C. Calculate the value of
.
|
a. |
1.62 kJ |
|
b. |
3.74 kJ |
|
c. |
14.2 kJ |
|
d. |
29.1 kJ |
|
e. |
32.9 kJ |
____ 48. Use the data given to calculate the value of K
for the reaction at 5°C.
AgCl(s) ®
Ag+(aq) + Cl-(aq)

|
a. |
9.76 ´ 10-1 |
|
b. |
7.68 ´ 10-7 |
|
c. |
1.76 ´ 10-10 |
|
d. |
2.61 ´ 10-11 |
|
e. |
5.10 ´ 10-13 |
____ 49. Identify the statement which best
explains the term "coupled reaction."
|
a. |
A reactant-favored reaction consumes the
products from a product-favored reaction. |
|
b. |
The heat released from an exothermic reaction
is used in a related endothermic reaction. |
|
c. |
The Gibbs free energy released from a
product-favored reaction is used to provide the energy for a reactant-favored
reaction to occur. |
|
d. |
A product-favored reaction supplies the activation
energy for another reaction. |
|
e. |
The Gibbs free energy released from a
product-favored reaction is released to the surroundings, causing an increase
in entropy. |
e- Chem
____ 50. Which is not an absolute indicator of a redox
reaction?
|
a. |
One reactant is a strong oxidizing
agent. |
|
b. |
One reactant is a strong reducing agent. |
|
c. |
At least one element changes oxidation
number. |
|
d. |
A pure element is present as a reactant
or a product. |
|
e. |
Oxygen is present. |
____ 51. The balanced reaction between aluminum metal
and aqueous cadmium(II) ion to produce cadmium metal and aqueous aluminum ion
in acidic solution is written
|
a. |
2Al(s)
+ 3Cd2+(aq) ® 2Al3+(aq) +
3Cd(s) |
|
b. |
3Al(s)
+ 2Cd2+(aq) ® 3Al3+(aq) +
2Cd(s) |
|
c. |
Al(s)
+ 3Cd2+(aq) ® 2Al3+(aq) +
Cd(s) |
|
d. |
6Al(s)
+ 6Cd2+(aq) ® 6Al3+(aq) +
6Cd(s) |
|
e. |
2Al(s)
+ 3Cd2+(aq) ® 3Al3+(aq) +
2Cd(s) |
Use this list of half-reactions to answer
the following questions.
|
MnO4-(aq) + 8H+(aq)
+ 5e- ® Mn2+(aq)
+ 4H2O(l) |
1.51 V |
|
Cr2O72-(aq)
+ 6e- ® 2Cr3+(aq)
+ 7H2O(l) |
1.33 V |
|
Pt2+(aq) + 2e- ® Pt(s) |
1.20 V |
|
Cu2+(aq) + 2e- ® Cu(s) |
0.34 V |
|
Pb2+(aq)+2e-®Pb(s) |
-0.13 V |
|
Al3+(aq)+3e-®Al(s) |
-1.66 V |
____ 53. Refer to Inst 19-1. Which combination of
reactants could be used to make an electrochemical cell?
|
a. |
Al3+(aq) and Cu(s) |
|
b. |
Pt(s) and Pb2+(aq) |
|
c. |
Cu(s) and MnO4-(aq) |
|
d. |
Cr2O72-(aq)
and MnO4-(aq) |
|
e. |
Al3+(aq) and Cr3+(aq) |
____ 54. The value of
for an aluminum-zinc electrochemical cell is
0.897 V at 25°C. Calculate
the value of DGº for this
cell.
|
a. |
-86.6 kJ |
|
b. |
-173 kJ |
|
c. |
-260. kJ |
|
d. |
-433 kJ |
|
e. |
-519 kJ |
____ 55. For a zinc-platinum electrochemical cell,
calculate the value of
when the concentration of Pt2+(aq)
is 0.050 M and the concentration of Zn2+(aq) is 1.1 M.
= 1.96 V under standard conditions. Pt is the
less active metal.
|
a. |
1.88 V |
|
b. |
1.92 V |
|
c. |
1.96 V |
|
d. |
2.00 V |
|
e. |
2.04 V |
____ 57. An electrolytic reaction is a system in which
|
a. |
a chemical reaction is used to produce
electricity. |
|
b. |
electricity is used to produce a
chemical reaction. |
|
c. |
the same element is both oxidized and
reduced. |
|
d. |
a reactant-favored reaction is forced to
produce electricity by the input of heat or light. |
|
e. |
the reaction conditions are manipulated
to change the value of |
____ 58. Which statement concerning the number of electrons
involved in electrolysis is not correct?
|
a. |
Electrons can be "counted" by
multiplying the current in amps by the time in seconds. |
|
b. |
The charge associated with one electron
is 96,500 coulombs. |
|
c. |
In producing one mole of Cl2(g)
from Cl-(aq), two moles of electrons are produced. |
|
d. |
When one mole of Fe is produced from Fe3+(aq),
three moles of electrons are needed. |
|
e. |
Electroplating of one mole of silver
from a solution of silver ions requires one mole of electrons. |
____ 59. Calculate the time needed to plate out 175 g
of nickel from a Ni2+ solution when a current of 10.0 A is applied.
|
a. |
938 hr |
|
b. |
32 hr |
|
c. |
16 hr |
|
d. |
8.0 hr |
|
e. |
4.0 hr |
85. Distinguish
between activation energy and the energy required to cause a reactant-favored
process to occur.
86. a. Use the
data given to determine whether refining aluminum from its ore, which is
primarily aluminum oxide, is product favored at 25°C. Be sure to write the balanced equation
before attempting to solve this problem.

b. This question could be extended to ask
the Kelvin or Celsius temperature at which the transition between
product-favored and reactant-favored occurs.
87. Consider the
reaction shown, with DG° = -32.8 kJ at 25°C. What is the value of DG when the pressure of nitrogen = 3.5 bar;
hydrogen = 1.2 bar; and ammonia = 0.22 bar? Explain the relationship between
your answer and the value of DG°; that is, does your answer make sense?
N2(g) + 3H2(g) ® 2NH3(g)
89. Write the
two half-reactions for the net redox reaction 2Al2O3(s) ® 4Al(s) + 3O2(g).
Explain how they can be used to write the balanced reaction.
90. Write the
balanced equation for the reaction between aluminum and dichromate ion in
acidic solution to produce aluminum ion and chromium(III) ion.
91. Explain the
relationship between the placement of the metals aluminum, zinc, iron, copper,
and silver on a table of reduction potentials and in an activity series. The
metals are listed in this question in order from most active to least active.
92. Use the
table of potentials shown as needed.
Pt2+(aq) + 2e- ® Pt(s) 1.20 V
Cu2+(aq) + 2e- ® Cu(s) 0.34 V
Pb2+(aq) + 2e- ® Pb(s) -0.13 V
Ga3+(aq) + 3e- ® Ga(s) -0.53 V
a. Write the balanced overall reaction for
gallium reacting with copper(II) ion.
b. Calculate the value of
for the reaction.
c. Determine the number of electrons
transferred in this reaction. Explain how you determined this answer.
d. Calculate the value of DG° for this cell at 25°C.
e. Calculate the value of the equilibrium
constant for this reaction at 25°C.
f. Is this reaction product-favored or reactant-favored? Explain
how your answers in parts b, d, and e support this conclusion.
Nuclear Reactions
____ 60. Gamma radiation is best described as
|
a. |
electrons ejected at high speeds from a
radioactive nucleus. |
|
b. |
a form of electromagnetic radiation that
is unaffected by magnetism. |
|
c. |
high-speed particles similar in size to
an electron, but oppositely charged. |
|
d. |
neutral particles that weigh
approximately one atomic mass unit. |
|
e. |
positive particles that are identical to
the nucleus of an atom of He-4. |
____ 61. In the reaction shown, the radiation produced
is a(an) _____.
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|
a. |
alpha particle |
|
b. |
beta particle |
|
c. |
gamma ray |
|
d. |
neutron |
|
e. |
positron |
____ 62. All of these are common modes of radioactive
decay except __________.
|
a. |
alpha emission |
|
b. |
beta emission |
|
c. |
electron capture |
|
d. |
positron emission |
|
e. |
phosphorescence |
____ 63. The rule that the mass number of stable
isotopes is always at least twice the atomic number is true for all nuclides
except
|
a. |
helium-3 |
|
b. |
beryllium-10 |
|
c. |
strontium-90 |
|
d. |
magnesium-28 |
|
e. |
vanadium-52 |
____ 64. Determine the number of Bq in 55 mCi. 1 Ci = 3.7 ´ 1010 dps and 1 Bq = 1 dps.
|
a. |
5.5 ´ 10-5 Bq |
|
b. |
1.4 ´ 10-3 Bq |
|
c. |
6.7 ´ 102 Bq |
|
d. |
2.0 ´ 106 Bq |
|
e. |
2.0 ´ 1012 Bq |
____ 65. An uncontrolled fission reaction occurs in a
_____.
|
a. |
nuclear reactor |
|
b. |
nuclear bomb |
|
c. |
x-ray machine |
|
d. |
particle accelerator |
|
e. |
cyclotron |
94. Explain in
your own words why iron is the most abundant heavy element in the universe.
95. "Since
radon is an alpha emitter, and alpha particles have a low penetrating power,
radon is not really as dangerous as the publicity implies." Is this
statement true or false? Support your answer with a detailed explanation.